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Electrophilic Substitution Reactions of Organosilanes, ..

Silicon in Organic Synthesis

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Vinyl Oxytrimethyl Silane - Monomers - Monomer …

(iii) A further way of producing cross-linking is to have an ethanoyl group in the silane. When these silicones are exposed to the air, the moisture reacts with the functional group, yielding a cross-linked silicone. An organometallic tin compound catalyses the reaction. These systems are often used as sealants and can be used in the home. The other product formed is ethanoic acid which can be recognized by its vinegary smell.
(iv) If some methyltrichlorosilane is added to the reactant, say dimethyldichlorosilane, the three chlorine atoms are hydrolyzed, thus producing a three dimensional network.

Vinyl Oxytrimethyl Silane - Monomers - 6213-94-1 ..

AB - A novel strategy for the diversity-oriented synthesis of multisubstituted olefins, where 2-pyridyldimethyl (vinyl)silane functions as a versatile platform for olefin synthesis, is described. The palladium-catalyzed Heck-type coupling of 2-pyridyldimethyl(vinyl)silanes with organic iodides took place in the presence of Pd2-(dba) 3/tri-2-furylphosphine catalyst to give β-substituted vinylsilanes in excellent yields. The Heck-type coupling occurred even with α- and β-substituted 2-pyridyldimethyl(vinyl)silanes. The one-pot double Heck coupling of 2-pyridyldimethyl(vinyl)silane took place with two different aryl iodides to afford β,β-diarylated vinylsilanes in good yields. The palladium-catalyzed Hiyama-type coupling of 2-pyridyldimethyl(vinyl)silane with organic halides took place in the presence of tetrabutylammonium fluoride to give di- and trisubstituted olefins in high yields. The sequential integration of Heck-type (or double Heck) coupling and Hiyama-type coupling produced the multisubstituted olefins in regioselective, stereoselective, and diversity-oriented fashions. Especially, the one-pot sequential Heck/Hiyama coupling reaction provides an extremely facile entry into a diverse range of stereodefined multisubstituted olefins. Mechanistic considerations of both Heck-type and Hiyama-type coupling reactions are also described.

Silane KH-550 - Amino Silane - Product center - …

3-Aminopropyltriethoxysilane CAS 919-30-2,Amino Silane

Silicones have unique properties amongst polymers because of the simultaneous presence of organic groups attached to a chain of inorganic atoms. They are used in many industries including those devoted to electronics, paints, construction and food.

Silicones are synthetic polymers with a silicon-oxygen backbone similar to that in silicon dioxide (silica), but with organic groups attached to the silicon atoms by C-Si bonds. The silicone chain exposes organic groups to the outside.


Organosilicon Reviews

(d) Silicone resins have a three-dimensional structure with the atoms arranged tetrahedrally about the silicon atoms. The resins are usually applied as a solution in an organic solvent, and are used as an electrical insulating varnish or for paints where water repellence is desired, for example, to protect masonry. They are also used to give an 'anti-stick' surface to materials coming into contact with 'sticky' materials such as dough and other foodstuffs.

Hydroxyl groups on the resin react with hydroxyl groups that are on the surfaces of various inorganic surfaces such as silica and glass, thus making the surface water-repellent.

Dow Corning offers a full range of silanes: organosilane, chlorosilane, epoxy silane, aminosilane, trichlorosilane, and more.
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Vinyl bromide synthesis by bromination or substitution

The most widely used silicones are those which have methyl groups along the backbone. Properties such as solubility in organic solvents, water-repellence and flexibility can be altered by substituting other organic groups for the methyls. For example, silicones with phenyl groups are more flexible polymers than those with methyl groups. They are also better lubricants and are superior solvents for organic compounds.
The structure of the repeating units of silicones can be represented as:

Vinyl Silane Alkylation with Imonium Salt.

The low surface tension of silicone fluids gives them unique surface properties. They are, for example, used as lubricants in polishes (a mixture of wax and a silicone fluid dissolved in an organic solvent), in paints and for water-proofing fabrics, paper and leather. They also have anti-foaming properties and have been used, for example, to suppress the foaming of detergents in sewage disposal plants.

Vinyl silanes offer a regio- and ..

(b) Silicone gels are based on the poly(dimethylsiloxane) chains but with a few cross-links between the chains, giving it a very open three-dimensional network. Often the cross-linking is done after a silicone fluid, together with a reactive group, is poured into a mould and then warmed or catalysed so that there is interaction to form cross-linking between the polymer chains. This is a very effective technique for protecting sensitive electronic equipment from damage from vibration and the polymer also acts as an electrical insulator. Pads containing a silicone gel are also used as shock absorbers in shoes, particularly in high-performance trainers and running shoes.

Copolymerization of Tris(methoxyethoxy)vinyl Silane …

A large range of silanes, known as coupling agents, has been developed to enable chemists to bond an inorganic substrate (such as glass, minerals and metals) to organic materials (for example, organic polymers such as the acrylics, polyamides, urethanes and polyalkenes).

Silane Crosslinked Polyethylene from Different Commercial PE ..

Silicon is first converted into chlorosilanes, e.g. RSiCl3, R2SiCl2 and R3SiCl, where R is an organic group.
When chloromethane is passed through heated silicon at about 550 K under slight pressure and in the presence of a copper catalyst (often copper itself but other copper-containing materials can be used, for example, brass or copper(II) chloride), a volatile mixture of chlorosilanes distils over. For example:

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