1H-2,1,3-Benzothiadiazin-4(3H)-one, 3-(1-methylethyl)-, 2,2-dioxide
Kamm, O., Segur, J. B. 2003. Methyl m-Nitrobenzoate. Organic Syntheses. 71.
Sharpless, Syntheses and Crystal Structures of the Cinchona Alkaloid Derivatives used as Ligands in the Osmium-Catalyzed Asymmetric Dihydroxylation of Olefins,
Zargarian, Synthesis of Optically Active Secondary Allylic Alcohols from Allylsilanes via Successive Asymmetric Dihydroxylation (AD) and Peterson Olefination Reactions, , 34, 2509 (1993
Sharpless, Syntheses of Diols by Catalytic Dihydroxylation Reactions, "Applied Homogeneous Catalysis by Organometallic Complexes", Boy Cornils and Wolfgang A.
Sharpless, Enantioselective Synthesis of Both Enantiomers of 7,7-Dimethyl-6,8-dioxabicyclo-[3.2.1]octane via Regioselective Asymmetric Dihydroxylation, , 1, 47 (1993) .
Fokin, Rapid Discovery and Structure-Activity Profiling of Novel Inhibitors of HIV-1 Protease Enabled by the Copper(I)-Catalyzed Synthesis of 1,2,3-Triazoles and Their Further Functionalization,
Sharpless, Asymmetric Dihydroxylation of Acrolein Acetals: Synthesis of Stable Equivalents of Enantiopure Glyceraldehyde and Glycidaldehyde, , 33, 2095 (1992).
Thiocyanic acid, (2-benzothiazolylthio)methyl ester
Sharpless, A Simple and Efficient Method for the Preparation of Pyridine--oxides II, , 39, 761 (1998).
1H-Benzotriazole, 4(or 5)-methyl-
Sharpless, Enantioselective Synthesis of Juvenile Hormone III in Three Steps from Methyl Farnesoate, , 8, 777 (1993).
1. Draw all resonance structures for the nitration of methyl benzoate occurring at the ortho, meta, and para positions. Be sure to include all charges.
Bring a clean, dry 25 x 150 mm test tube to the storeroom manager and trade it in for a 6.2 mL (6.8 g, 0.050 moles) sample of methyl benzoate (weigh the sample before you begin to obtain an exact weight). Place 14.5 mL (26.7 g) of concentrated sulfuric acid in a 125 rnL Erlenmeyer flask, cool it to 0 °C in an ice/water bath, then add all of the methyl benzoate with swirling.
Sharpless, Asymmetric Epoxidation Provides Shortest Routes to Four Chiral Epoxy Alcohols which are Key Intermediates in Syntheses of Methymycin, Erythromycin, Leukotriene C-1 and Disparlure,
In this experiment, you will synthesize methyl-m-nitrobenzoate from methyl benzoate via electrophilic aromatic substitution. The isolated product will be purified by recrystallization, and purity will be determined from the melting point.
Benzoic acid, 4-hydroxy-, phenylmethyl ester
L-Ascorbic acid, 2-[(2R)-3,4-dihydro-2,5,7,8-tetramethyl-2-[(4R,8R)-4,8,12-trimethyltridecyl]-2H-1-benzopyran-6-YL hydrogen phosphate], potassium salt (1:1)
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